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| Registros recuperados: 17 | |
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| Alpat,Senol; Alpat,Sibel Kilinç; Çadirci,Bilge Hilal; Özbayrak,Özge; Yasa,Ihsan. |
| Circinella sp. was employed as a biosorbent for removal of Ni(II) from aqueous solution. The biosorption kinetics and isotherms were investigated. The effect of several parameters, such as biosorbent dosage, contact time, initial concentration, pH and temperature, on biosorption process was evaluated. The kinetic studies indicated that the biosorption followed pseudo-second order kinetic model. Biosorption behaviour of Ni(II) on Circinella sp. was expressed by both Langmuir and Freundlich isotherms. The equilibrium data fit better to the Langmuir model compared to the Freundlich model in concentration range studied (1.0-3.0 mM). The thermodynamic parameters (ΔG0, ΔH0 and ΔS0) were also determined, and it was found that the Ni(II)... |
| Tipo: Journal article |
Palavras-chave: Biosorption; Circinella sp; Equilibrium; Kinetic; Nickel. |
| Ano: 2010 |
URL: http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-34582010000500004 |
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| CORREIA, F. H.; CURADO, I. C.; GHESTI, G. F.; BRAGA, P. R. S.; MARINHO, A. L. A.; MATTOS, L. V.; NORONHA, F. B.; SOARES, I. P.; SCHULTZ, E. L.. |
| Ni-Mg-Al mixed oxides derived from hydrotalcite-like compounds were prepared by a co-precipitation technique, calcined at two temperatures (550 °C and 750 °C) and applied to steam reforming of simulated biogas. Three nickel contents were used in the catalysts (5, 10 and 15%). The catalysts were characterized by X ray fluorescence, N2 sorption techniques, X-ray diffraction and temperature-programmed desorption of CO2. Steam reforming experiments using simulated biogas were carried out at atmospheric pressure and 750 °C, using S/C ratio of 3.2. Catalysts calcined at 750 °C showed nickel and magnesium aluminate phases, resulting in lower density of basic sites. Conversion of CH4 ranged from 97.4 to 99.6% while CO2 conversion ranged from 58.5 to 63.5%. The... |
| Tipo: Boletim de Pesquisa e Desenvolvimento (INFOTECA-E) |
Palavras-chave: Steam reforming; Mixed oxides; Biogás; Níquel; Oxido; Steam; Nickel; Catalysts; Oxides. |
| Ano: 2020 |
URL: http://www.infoteca.cnptia.embrapa.br/infoteca/handle/doc/1124168 |
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| Shweta,Mishra; Agrawal,S.B.. |
| The impact of supplemental UV-B (sUV-B) radiation and heavy metals: Cd (68 µmol.kg-1 soil) and Ni (68 µmol.kg-1 soil) singly and in combination was studied on photosynthetic and non-photosynthetic pigments, metabolites, enzyme activities, biomass accumulation and the net primary productivity of spinach (Spinacia oleracea L. var. All Green), a common leafy vegetable plant. Both the stresses individually and in combination resulted in the reduction of photosynthetic pigments, ascorbic acid, and catalase activity, whereas a reverse trend was observed for anthocyanin, flavonoids and proline content, lipid peroxidation and peroxidase activity. The interactive effects of both the stresses were, however, less than additive. Combined treatment of sUV-B + Cd was... |
| Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Spinaicia oleracea; Biomass; Cadmium; Enzymes; Nickel; Pigments; Ultraviolet-B. |
| Ano: 2006 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1677-04202006000200007 |
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| Ratie, G.; Quantin, C.; Jouvin, D.; Calmels, D.; Ettler, V.; Sivry, Y.; Cruz Vieira, L.; Ponzevera, Emmanuel; Garnier, J.. |
| Nickel isotope ratios were measured in ores, fly ash, slags and FeNi samples from two metallurgical plants located in the Goiás State, Brazil (Barro Alto, Niquelândia). This allowed investigating the mass-dependent fractionation of Ni isotopes during the Ni-laterite ore smelting and refining. Feeding material exhibits a large range of δ60Ni values (from 0.02 ± 0.10 ‰ to 0.20 ± 0.05 ‰, n=7), explained by the diversity of Ni-bearing phases, and the average of δ60Nifeeding materials was found equal to 0.08 ± 0.08‰ (2SD, n=7). Both δ60Ni values of fly ash (δ60Ni = 0.07 ± 0.07‰, n=10) and final FeNi produced (0.05 ± 0.02 ‰, n=2) were not significantly different from the feeding materials ones. These values are consistent with the very high production yield of... |
| Tipo: Text |
Palavras-chave: Nickel; Isotope; Smelting; Refining; Source; Soil. |
| Ano: 2016 |
URL: http://archimer.ifremer.fr/doc/00278/38961/37501.pdf |
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| Ratie, G.; Jouvin, D.; Garnier, Julien; Rouxel, Olivier; Miska, S.; Guimaraes, E.; Cruz Vieira, L.; Sivry, Y.; Zelano, I.; Montarges-pelletier, E.; Thil, F.; Quantin, C.. |
| Although Ni isotopes have been shown to be significantly fractionated in terrestrial samples, their use in continental environmental studies has not yet been evaluated. The present study focuses on an ultramafic (UM) massif (Barro Alto, Goias, Brazil) because such areas are naturally rich in Ni. We present developed lateritic weathering profiles. The goal of the study is to evaluate the potential of using Ni isotopes in environmental continental studies by combining its isotopic signature with mineralogy, in order to better understand the geochemical cycling of Ni in UM settings during weathering. As such, Ni isotope values were measured in samples from the Barro Alto UM complex in the main stages of the lateritic weathering profile of UM rocks, including... |
| Tipo: Text |
Palavras-chave: Nickel; Isotope; Weathering; Mineralogy; Soil. |
| Ano: 2015 |
URL: https://archimer.ifremer.fr/doc/00254/36553/35098.pdf |
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| Gueguen, Bleuenn; Rouxel, Olivier; Ponzevera, Emmanuel; Bekker, Andrey; Fouquet, Yves. |
| Although initial studies have demonstrated the applicability of Ni isotopes for cosmochemistry and as a potential biosignature, the Ni isotope composition of terrestrial igneous and sedimentary rocks, and ore deposits remains poorly known. Our contribution is fourfold: (a) to detail an analytical procedure for Ni isotope determination, (b) to determine the Ni isotope composition of various geological reference materials, (c) to assess the isotope composition of the Bulk Silicate Earth relative to the Ni isotope reference material NIST SRM 986 and (d) to report the range of mass-dependent Ni isotope fractionations in magmatic rocks and ore deposits. After purification through a two-stage chromatography procedure, Ni isotope ratios were measured by MC-ICP-MS... |
| Tipo: Text |
Palavras-chave: Nickel; Stable isotopes; MC-ICP-MS; Geological reference materials; Bulk Silicate Earth; Abiotic fractionation. |
| Ano: 2013 |
URL: http://archimer.ifremer.fr/doc/00159/27069/25332.pdf |
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| Prasad,Majeti Narasimha Vara. |
| Nickeliferous soils are invaded predominantly by members of the Brassicaceae, Cyperaceae, Cunoniaceae, Caryophyllaceae, Fabaceae, Flacourtiaceae, Euphorbiaceous, Lamiaceae, Poaceae and Violaceae, and many of these plants are metal tolerant. About 300 Ni hyperaccumulating plants been identified. These members exhibit unusual appetite for toxic metals and elemental defense. Hyperaccumulators provide protection against fungal and insect attack. Investigations suggested that Ni-hyperaccumulation has a protective function against fungal and bacterial pathogens in Streptanthus polygaloides and Thlaspi montanum. Significance of nickelophilous plants and their significance in phytotechnologies are discussed in this paper. |
| Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Heavy metal; Hyperaccumulators; Nickel; Phytomanagement; Tolerance. |
| Ano: 2005 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1677-04202005000100010 |
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| Marchi,Giuliano; Guelfi-Silva,Douglas Ramos; Malaquias,Juaci Vitória; Guilherme,Luiz Roberto Guimarães; Spehar,Carlos Roberto; Martins,Eder de Souza. |
| Abstract: The objective of this work was to evaluate the solubility of the micronutrients copper, nickel, and zinc, chemically extracted from silicate agrominerals, as alternative sources of potassium for lettuce (Lactuca sativa) and rice (Oryza sativa) cultures, as well as their availability to the plants. The micronutrient contents of five agrominerals (alkaline ultramafic, biotite schist, volcanic breccia, phlogopite schist, and mining by-product from Chapada) were evaluated, after being extracted by the citric acid, hydrochloric acid, diethylenetriaminepentaacetic acid, 3051A, neutral ammonium citrate, and Mehlich-3 methods. The agrominerals, at the doses of 0 (control), 200, 400, and 600 kg ha-1 K, were mixed to soil where lettuce and rice were... |
| Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Copper; Mining by-product; Nickel; Nutrient availability; Zinc. |
| Ano: 2020 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-204X2020000100600 |
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| Ratie, G.; Quantin, C.; Maia De Freitas, A.; Echevarria, G.; Ponzevera, Emmanuel; Garnier, J.. |
| Ultramafic derived soils are characterized by low nutrient soils, a low Ca:Mg ratio, and high metal contents such as Ni, Co and Cr. The vegetation growing on these soils is highly adapted and includes both Ni hyperaccumulator and accumulator species. Today, approximately 530 Ni hyperaccumulator species are listed worldwide and the Ni concentration can be extremely high, e.g. up to 25% in latex from Pycnandra acuminata (Sapotaceae), a tree found in New Caledonia. The aim of this study is to identify the potential role of Ni hyperaccumulator plants in the Ni biogeochemical cycle at the soil surface by using Ni isotopes. A set of Ni hyperaccumulator and Ni accumulator plants as well as topsoils were sampled on the Barro Alto and Niquelândia ultramafic... |
| Tipo: Text |
Palavras-chave: Nickel; Isotope; Ni hyperaccumulator species; Ultramafic environment. |
| Ano: 2019 |
URL: https://archimer.ifremer.fr/doc/00464/57565/59740.pdf |
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| Wang, Xudong; Bayon, Germain; Kim, Jung-hyun; Lee, Dong-hun; Kim, Dahae; Guéguen, Bleuenn; Rouget, Marie-laure; Barrat, Jean-alix; Toffin, Laurent; Feng, Dong. |
| Seeping of methane-rich fluids at submarine cold seeps drives intense microbial activity and precipitation of authigenic carbonates. Some trace elements play an important role in the biogeochemical processes operating at cold seeps, especially as specific enzymatic co-factors related to methanogenesis and the anaerobic oxidation of methane (AOM). However, it is unclear whether microbial trace metal utilization can be traced by the geochemical composition of seep carbonates. In this study, we analyzed a series of authigenic carbonate samples recovered from various seep settings worldwide and report for the first time trace element concentrations for total lipid fractions, combined with biomarker analyses and determination of elemental abundances in... |
| Tipo: Text |
Palavras-chave: Seep carbonate; Lipid compounds; Trace elements; Tungsten; Nickel; Cobalt; Molybdenum. |
| Ano: 2019 |
URL: https://archimer.ifremer.fr/doc/00511/62311/66562.pdf |
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| Registros recuperados: 17 | |
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